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Effects of addition of hindered phenol compounds to a segmented polyurethane with shape memory on mechanical yielding

机译:Effects of addition of hindered phenol compounds to a segmented polyurethane with shape memory on mechanical yielding

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摘要

The mechanical yielding behavior of the shape memory polyurethane (SMP) and its composite samples were investigated to verify the effect of addition of hindered phenol. The composite samples were prepared using SMP as matrix and hindered phenol (AO-80) as filler, and then tensile tests were carried out at a range of temperatures and with different fixed crosshead speeds. According to the tensile data at 25 °C, the yield stress was increased by adding AO-80. In terms of the Eyring theory, the activation volume of deformation units decreased with increase of the amount of AO-80 added. This is because the packing of the hard segments is enhanced by addition of AO-80. Consequently, it was suggested that the yield process is caused by the rotation of hard segment domains within the deformed plastic domains composed of glassy soft segments. © 2010 Springer Science+Business Media, LLC.
机译:研究了形状记忆聚氨酯(SMP)及其复合材料样品的机械屈服行为,以验证添加受阻酚的效果。使用SMP作为基质和受阻酚(AO-80)作为填料制备复合材料样品,然后在一定温度范围内以不同的固定十字头速度进行拉伸测试。根据25°C时的拉伸数据,通过添加AO-80可增加屈服应力。根据Eyring理论,变形单元的激活量随AO-80添加量的增加而降低。这是因为通过添加AO-80可以增强硬段的填充。因此,有人提出屈服过程是由在由玻璃状软链段组成的变形塑性区域内的硬链段区域的旋转引起的。 ©2010 Springer Science + Business Media,LLC。

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